| Entry into force: | 14 February 1991, in accordance with article 15 (1). |
| Registration: | 14 February 1991, No. 27874. |
| Status: | Signatories: 25 ,Parties: 31. |
| Text: | Depositary notification C.N.252.1988.TREATIES-1 of 6 December 1988. |
Note: The Protocol was drawn up within the framework of the Economic Commission for Europe and was adopted on 31 October 1988 by the Executive Body for the Convention on Long-Range Transboundary Air Pollution. It was open for signature at Sofia from 1 to 4 November 1988 and subsequently, at the Headquarters of the United Nations in New York until 5 May 1989.
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| Participant | Signature | Ratification, Acceptance (A), Approval (AA), Accession (a), Succession (d) |
| Austria | 1 Nov 1988 | 15 Jan 1990 |
| Belarus | 1 Nov 1988 | 8 Jun 1989 A |
| Belgium | 1 Nov 1988 | 8 Nov 2000 |
| Bulgaria | 1 Nov 1988 | 30 Mar 1989 |
| Canada | 1 Nov 1988 | 25 Jan 1991 |
| Cyprus | 2 Sep 2004 a | |
| Czech Republic1 | 30 Sep 1993 d | |
| Denmark2 | 1 Nov 1988 | 1 Mar 1993 A |
| Estonia | 7 Mar 2000 a | |
| European Community | 17 Dec 1993 a | |
| Finland | 1 Nov 1988 | 1 Feb 1990 |
| France | 1 Nov 1988 | 20 Jul 1989 AA |
| Germany3 | 1 Nov 1988 | 16 Nov 1990 |
| Greece | 1 Nov 1988 | 29 Apr 1998 |
| Hungary | 3 May 1989 | 12 Nov 1991 AA |
| Ireland | 1 May 1989 | 17 Oct 1994 |
| Italy | 1 Nov 1988 | 19 May 1992 |
| Liechtenstein | 1 Nov 1988 | 24 Mar 1994 |
| Lithuania | 26 May 2006 a | |
| Luxembourg | 1 Nov 1988 | 4 Oct 1990 |
| Netherlands4 | 1 Nov 1988 | 11 Oct 1989 A |
| Norway | 1 Nov 1988 | 11 Oct 1989 |
| Poland | 1 Nov 1988 | |
| Russian Federation | 1 Nov 1988 | 21 Jun 1989 A |
| Slovakia1 | 28 May 1993 d | |
| Slovenia | 5 Jan 2006 a | |
| Spain | 1 Nov 1988 | 4 Dec 1990 |
| Sweden | 1 Nov 1988 | 27 Jul 1990 |
| Switzerland | 1 Nov 1988 | 18 Sep 1990 |
| Ukraine | 1 Nov 1988 | 24 Jul 1989 A |
| United Kingdom of Great Britain and Northern Ireland5 | 1 Nov 1988 | 15 Oct 1990 |
| United States of America | 1 Nov 1988 | 13 Jul 1989 A |
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Upon signature:
Statement:
"In accordance with Article 2, paragraph 1 of the protocol, the Government of the United States of America specifies 1978 as the applicable calendar year for determining measures to control and/or reduce its national annual emissions of nitrogen oxides or their transboundary fluxes.
The Government of the United States of America believes that there must be a follow-on protocol to establish a control obligation based on scientific, technical and economic factors, including consideration of the protocol's effect on the innovative control technologies program of the United States. If such a protocol is not adopted by 1996, the United States of America will consider withdrawal from this protocol.
The Government of the United States of America understands that nations will have the flexibility to meet the overall requirements of the protocol through the most effective means."
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1. Czechoslovakia had signed and approved the Protocol on 1 November 1988 and 17 August 1990, respectively. See also note 1 under "Czech Republic" and note 1 under "Slovakia" in the "Historical Information" section in the front matter of this volume.
2. With a declaration of non-application to the Faroe Islands and Greenland.
3. The German Democratic Republic had signed the Protocol on 1 November 1988.
See also note 2 under "Germany" in the "Historical Information" section in the front matter of this volume.
5. The instrument specifies that the said Protocol is ratified in respect of the United Kingdom of Great Britain and Northern Ireland, the Bailiwick of Jersey, the Bailiwick of Guernsey, the Isle of Man and the Sovereign Base Areas of Akrotiri and Dhekelia in the island of Cyprus.